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The abundance of H2 in molecular clouds, relative to the commonly used tracer CO, has only been measured toward a few embedded stars, which may be surrounded by atypical gas. We present observations of near-infrared absorption by H2, CO,…

Astrophysics of Galaxies · Physics 2017-03-30 John H. Lacy , Christopher Sneden , Hwihyun Kim , Daniel T. Jaffe

CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…

Chemical Physics · Physics 2015-06-17 Carina Arasa , Marc C. van Hemert , Ewine F. van Dishoeck , Geert-Jan Kroes

We present the detection of carbon monoxide molecules (CO) at z=1.6408 towards the quasar SDSSJ160457.50+220300.5 using the VLT Ultraviolet and Visual Echelle Spectrograph. CO absorption is detected in at least two components in the first…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-13 P. Noterdaeme , C. Ledoux , R. Srianand , P. Petitjean , S. Lopez

Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV…

Chemical Physics · Physics 2020-11-05 Rémi Dupuy , Michal Haubner , Bernard Henrist , Jean-Hugues Fillion , Vincent Baglin

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Instrumentation and Methods for Astrophysics · Physics 2021-02-22 R. Basalgète , R. Dupuy , G. Féraud , C. Romanzin , L. Philippe , X. Michaut , J. Michoud , L. Amiaud , A. Lafosse , J-H. Fillion , M. Bertin

We performed a systematic analysis of the 4.67 $\mu$m CO ro-vibrational absorption band toward nearby active galactic nuclei (AGNs) and analyzed the absorption profiles of ten nearby galaxies collected from the AKARI and Spitzer…

Astrophysics of Galaxies · Physics 2018-01-24 S. Baba , T. Nakagawa , N. Isobe , M. Shirahata

The physical and chemical properties of cold and dense molecular clouds are key to understanding how stars form. Using the IRAM 30 m and NRO 45 m telescopes, we carried out a Multiwavelength line-Imaging survey of the 70 $\mu$m dark and…

Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in…

Planet atmosphere and hydrosphere compositions are fundamentally set by accretion of volatiles, and therefore by the division of volatiles between gas and solids in planet-forming disks. For hyper-volatiles such as CO, this division is…

Earth and Planetary Astrophysics · Physics 2019-09-25 Alexia Simon , Karin I. Oberg , Mahesh Rajappan , Pavlo Maksiutenko

Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…

Astrophysics of Galaxies · Physics 2023-01-04 A. Taillard , V. WakelaM , P. Gratier , E. Dartois , M. Chabot , J. A. Noble , J. V. Keane , A. C. A. Boogert , D. Harsono

We present temperature programmed desorption (TPD) measurements of CO, CH$_4$, O$_2$ and CO$_2$ from the forsterite(010) surface in the sub-monolayer and multilayer coverage regimes. In the case of CO, CH$_4$ and O$_2$, multilayer growth…

Astrophysics of Galaxies · Physics 2017-09-20 T. Suhasaria , J. D. Thrower , H. Zacharias

CO oxidation on Ru(0001) is a long-standing example of a reaction that, being thermally forbidden in ultra-high vacuum, can be activated by femtosecond laser pulses. In spite of its relevance, the precise dynamics of the photo-induced…

Materials Science · Physics 2022-09-08 Auguste Tetenoire , Christopher Ehlert , J. I. Juaristi , Peter Saalfrank , M. Alducin

We report an investigation of X-ray induced desorption of neutrals, cations and anions from CO ice. The desorption of neutral CO, by far the most abundant, is quantified and discussed within the context of its application to astrochemistry.…

Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…

The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore)…

Context. While radiative cooling of interstellar grains is a well-known process, little detail is known about the cooling of grains with an icy mantle that contains volatile adsorbed molecules. Aims. We explore basic details for the cooling…

Astrophysics of Galaxies · Physics 2020-02-05 Juris Kalvans , Juris Roberts Kalnin

In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…

Astrophysics of Galaxies · Physics 2022-09-07 Alec Paulive , Joshua T. Carder , Eric Herbst

The work is devoted to the adaptation of the results of laboratory studies of the laser-induced dissociation of molecules of benzene adsorbed on a quartz substrate to the conditions of the interstellar medium. Adsorption was performed under…

Astrophysics of Galaxies · Physics 2019-08-14 M. S. Murga , V. N. Varakin , A. V. Stolyarov , D. S. Wiebe

We present new results on CO depletion in a sample of nearby pre-stellar cores, based on observations of the millimeter C17O and C18O lines and the 1.3 mm dust emission with the IRAM 30m telescope. In most cases, the distribution of CO is…

Volatile organic molecules formed by photochemistry in the upper atmosphere of Titan can undergo condensation as pure ices in the stratosphere and the troposphere as well as condense as ice layers onto the organic aerosols that are visible…

Earth and Planetary Astrophysics · Physics 2019-04-02 Benjamin Fleury , Murthy S. Gudipati , Isabelle Couturier-Tamburelli , Nathalie Carrasco
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