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The procedure has been developed for extracting homocharge and heterocharge currents from experimentally measured thermally stimulated depolarization currents of corona poled PVDF. Application of different depolarization modes supplemented…

Materials Science · Physics 2007-05-23 S. N. Fedosov , A. F. Butenko , A. E. Sergeeva

Experimental evidence is provided on close relation between polarization and space charge in corona poled PVDF films. It is shown that the depolarizing field is compensated by charges trapped in macroscopic transition zones, by which…

Materials Science · Physics 2007-05-23 A. F. Butenko , S. N. Fedosov , A. E. Sergeeva

Experimental results are presented on anomalous behavior of absorption currents in PVDF during the stepwise increase of the voltage applied through a corona. These results, supplemented with the dynamics of the time constant of the electret…

Materials Science · Physics 2009-02-27 A. F. Butenko

Corona charging a free-standing polymer film can produce a quasi-permanent potential difference across the film thickness, while the absolute amplitude of surface voltage may be highly sensitive to the free charges. To precisely control the…

Applied Physics · Physics 2020-06-01 Rui Kou , Ying Zhong , Yu Qiao

We have compared measurements of a set of polyethylene terephthalate (PET) electret samples by means of pulsed electroacoustic method (PEA) and thermally stimulated depolarization current (TSDC) techniques. Experimental parameters such as…

Materials Science · Physics 2022-03-09 S. E. Parsa , J. C. Cañadas , J. A. Diego , M. Mudarra , J. Sellarès

Polyvinylidenefluoride (PVDF) a semicrystalline pieozoelectric polymer was synthesized with varying process conditions and its ferroelectric domain orientations were studied using piezoresponse force microscope (PFM). PVDF thin films…

We consider ferroelectric phase transitions in both short-circuited and biased ferroelectric-semiconductor films with a space (depletion) charge which leads to some unusual behavior. It is shown that in the presence of the charge the…

Statistical Mechanics · Physics 2009-10-31 A. M. Bratkovsky , A. P. Levanyuk

We measure the remnant polarization of ferroelectric domains in BiFeO3 films down to 3.6 nm using low energy electron and photoelectron emission microscopy. The measured polarization decays strongly below a critical thickness of 5-7 nm…

Materials Science · Physics 2013-01-04 J. E. Rault , W. Ren , S. Prosandeev , S. Lisenkov , D. Sando , S. Fusil , M. Bibes , A. Barthelemy , L. Bellaiche , N. Barrett

A measurement technique is presented to quantify the polarization loss in ferroelectric thin films as a function of delay time during the first 100s after switching. This technique can be used to investigate charge trapping in ferroelectric…

Four modifications of the corona triode are described for charging polar polymers with ferroelectric or non-linear optical properties. Advantages of the constant current modification of corona poling are illustrated and discussed.

Materials Science · Physics 2007-05-23 S. N. Fedosov , A. E. Sergeeva , T. A. Revenyuk , A. F. Butenko

In this work, the effect of flashing corona enhancement by introducing Teflon dielectric enclosure in vicinity to the electrode assembly was studied. The discharge operating in air without the dielectric was able to operate within a very…

Plasma Physics · Physics 2019-08-13 Xingxing Wang , Andrei Khomenko , Alexey Shashurin

Ferroelectrets are piezoelectrically-active polymer foams that can convert externally applied loads into electric charge. Existing processing routes used to create pores of the desired geometry and degree of alignment appropriate for…

Applied Physics · Physics 2019-02-06 Yan Zhang , Chris R. Bowen , Sylvain Deville

We use first principles methods to study static and dynamical mechanical properties of the ferroelectric polymer Poly(vinylidene fluoride) (PVDF) and its copolymer with trifluoro ethylene (TrFE). We use density functional theory [within the…

Soft Condensed Matter · Physics 2009-11-10 H. B. Su , Alejandro Strachan , William A. Goddard

The transient electric current of surfactants dissolved in a nonpolar solvent is investigated both experimentally and theoretically in the parallel-plate geometry. Due to a low concentration of free charges the cell can be completely…

Soft Condensed Matter · Physics 2015-05-30 Pavel Kornilovitch , Yoocharn Jeon

An emerging area in condensed matter physics is the use of multilayered heterostructures to enhance ferroelectricity in complex oxides. Here, we demonstrate that optically pumping carriers across the interface between thin films of a…

Materials Science · Physics 2013-07-12 Y. M. Sheu , S. A. Trugman , L. Yan , C. -P. Chuu , Z. Bi , Q. X. Jia , A. J. Taylor , R. P. Prasankumar

Poly(ethylene terephthalate) (PET), as most dielectric materials, is able to retain space charge in traps. This allows the material to attain an almost-permanent polarization when space charge is displaced by an external electric field or…

Materials Science · Physics 2019-02-20 J. C. Cañadas , J. A. Diego , M. Mudarra , S. E. Parsa , J. Sellarès

It is shown that surface conduction can stabilize electrodeposition in random, charged porous media at high rates, above the diffusion-limited current. After linear sweep voltammetry and impedance spectroscopy, copper electrodeposits are…

Chemical Physics · Physics 2016-03-24 Ji-Hyung Han , Miao Wang , Peng Bai , Fikile R. Brushett , Martin Z. Bazant

The relaxation of atomic polarization in buffer-gas-free, paraffin-coated cesium vapor cells is studied using a variation on Franzen's technique of ``relaxation in the dark'' [Franzen, Phys. Rev. {\bf 115}, 850 (1959)]. In the present…

We report on the rejuvenation of thin films of polystyrene (PS) as they are heated from stable glassy states - prepared either through vapour deposition or physical aging. For films with thickness $h \gtrsim 200$ nm, the rejuvenation of…

Soft Condensed Matter · Physics 2024-08-22 Saba Karimi , Junjie Yin , James A. Forrest

Isothermal polarization and depolarization currents in polystyrene doped with DR1 chromophore molecules have been measured and analyzed in order to study the electrical relaxation of the poled order in this guest-host system. It has been…

Materials Science · Physics 2007-05-23 S. N. Fedosov , T. A. Revenyuk , J. A. Giacometti
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