Atomic Physics
We have performed microwave spectroscopy of sodium least-bound molecular states, improving the precision of the knowledge of their energies at zero magnetic field by almost three orders of magnitude. Our experimental observations give us…
The nature of atomic vapors, their natural alignment with interatomic transitions, and their ease of use make them highly suited for spectrally narrow-banded optical filters. Atomic filters come in two flavors: a filter based on the…
Mendeleev's periodic table successfully groups atomic elements according to their chemical and spectroscopic properties. However, it becomes less sufficient in describing the electronic properties of highly charged ions (HCIs) in which many…
We present the ExoAtom database, www.exomol.com/exoatom, an extension of the ExoMol database to provide atomic line lists in the ExoMol format. ExoAtom is designed for detailed astrophysical, planetary, and laboratory applications. ExoAtom…
Conventional practice of spatially resolved detection in diffusion-coupled thermal atomic vapors implicitly treat localized responses as mutually independent. However, in this study, it is shown that observable correlations are governed by…
Precision measurements of the electron's electric dipole moment (eEDM) are critical for testing fundamental symmetries in particle physics, and heavy polar molecules-such as barium monofluoride (BaF)-have emerged as promising candidates for…
This work has investigated the Magneto-Optical Trap (MOT) system used to produce Bose-Einstein Condensate (BEC). A primary challenge addressed in this study concerns the geometric limitations of traditional single-pair anti-Helmholtz coil…
We present relativistic many-body perturbation theory plus configuration interaction (MBPT+CI) calculations of the lowest four excited states of Ni$^{12+}$, a promising candidate for highly charged ion (HCI) optical clocks. By combining the…
Stability achieved by large angular momentum is ubiquitous in nature, with examples ranging from classical mechanics, over optics and chemistry, to nuclear physics. In atoms, angular momentum can protect excited electronic orbitals from…
Technologies for manipulating single atoms have advanced drastically in the past decades. Due to their excellent controllability of internal states, atoms serve as one of the ideal platforms as quantum systems. One major research direction…
The static and dynamic electric dipole polarizabilities of the $5s^2~^1\!S_0$ and $5s5p~^3\!P_{0,2}$ states of Sr atoms are calculated using the relativistic configuration interaction plus the many-body perturbation theory (RCI+MBPT)…
Within the framework of the second-order non-relativistic quantum perturbation theory, the methods of the theory of irreducible tensor operators, and nonorthogonal orbitals, the absolute values and shape of the generalized cross-sections of…
We demonstrate a three-dimensional magneto-optical trap (MOT) of a metal hydride molecule, CaH. We are able to scatter $\sim$$10^{4}$ photons with vibrational loss covered up to vibrational quantum number $\nu=2$. This allows us to laser…
Divalent atoms have emerged as powerful alternatives to alkalis in ultracold atom platforms, offering unique advantages arising from their two-electron structure. Among these species, ytterbium (Yb) is especially promising, yet its anionic…
We report high-precision frequency ratio measurements between optical atomic clocks based on $^{27}$Al$^+$, $^{171}$Yb, and $^{87}$Sr. With total fractional uncertainties at or below $3.2 \times 10^{-18}$, these measurements meet an…
We study the classical dynamics of a Paul-trapped ion in a low-density bath of atoms above 1 $\mu\textrm{K}$. We find that lower energy collisions with more massive atoms, especially at energies less than the initial micromotion heating,…
The excitation energy of $ {}^{229m} \mathrm{Th} $ is extremely low at $ 8.4 \, \mathrm{eV} $; thus, this isotope exhibits changes in its decay modes depending on the chemical state, specifically the outermost electronic states. However,…
We present the quantum-mechanical calculations of the dimensionless sensitivity coefficients Q to small changes in the fundamental physical constant mu = m_e/m_p - the electron-to-proton mass ratio - for a number of low-frequency (1-50 GHz)…
Hyper-Ramsey protocols effectively reduce AC-Stark shifts in probing ultra-narrow optical clock transitions but they remain sensitive to laser intensity noise, decoherence, frequency drifts, and low-frequency perturbations. We address these…
The electronic energy level structure of yttrium monoxide (YO) provides a long-lived, low-lying $^{2}\Delta$ state ideal for high-precision molecular spectroscopy, narrowline laser cooling at the single photon-recoil limit, and studying…