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Zeeman split Kramers doublets in spin-supersolid candidate Na$_{2}$BaCo(PO$_{4}$)$_{2}$

Strongly Correlated Electrons 2025-12-24 v1 Materials Science

Abstract

Na2_{2}BaCo(PO4_{4})2_{2} is a triangular antiferromagnet that displays highly efficient adiabatic demagnetization cooling (J. Xiang et al.\textit{et al.} Nature 625{\bf{625}}, 270 (2024)) near a quantum critical point at μ0Hc1.6\mu_{0}H_{c}\sim 1.6 T, separating a low-field magnetically disordered from a high-field fully polarized ferromagnetic phase. We apply high resolution backscattering neutron spectroscopy in an applied field to study the magnetic excitations near μ0Hc\mu_{0}H_{c}. At large fields we observe ferromagnetic fluctuations that gradually transition to being overdamped in energy below μ0Hc\mu_{0}H_{c} where the magnetism is spatially disordered. We parameterize the excitations in the high field polarized phase in terms of coupled Zeeman split Kramers doublets originating from the presence of spin-orbit coupling. On reducing the field, the splitting between the Kramers doublets is reduced and if done adiabatically, provides a mechanism for reducing temperature. On lowering the applied field through the μ0Hc\mu_{0}H_{c} the excitations characterize a textured phase that we suggest is inefficient for cooling. Low temperature disordered frustrated magnets built on Kramers doublets with nearby quantum critical points provide a route for efficient magnetocalorics.

Keywords

Cite

@article{arxiv.2503.00462,
  title  = {Zeeman split Kramers doublets in spin-supersolid candidate Na$_{2}$BaCo(PO$_{4}$)$_{2}$},
  author = {T. I. Popescu and N. Gora and F. Demmel and Z. Xu and R. Zhong and T. J. Williams and R. J. Cava and G. Xu and C. Stock},
  journal= {arXiv preprint arXiv:2503.00462},
  year   = {2025}
}

Comments

(main text - 5 pages, 4 figures; supplementary information - 7 pages, 7 figures, to be published in Physical Review Letters)