English

Virial expansion and condensation with a new generating function

Statistical Mechanics 2015-06-22 v2 High Energy Physics - Phenomenology

Abstract

Mayer's convergence method for virial expansion and condensation is studied using a new generating function for canonical partition function, which directly depends on irreducible cluster integral, βk\beta_k, unlike Mayer's work where it depends on reducible cluster integral, blb_l. The virial expansion, criteria for it's validity and criteria for condensation, etc. are derived from our generating function. All earlier Mayer's results are obtained from this new generating function.

Keywords

Cite

@article{arxiv.1407.0277,
  title  = {Virial expansion and condensation with a new generating function},
  author = {Vishnu M. Bannur},
  journal= {arXiv preprint arXiv:1407.0277},
  year   = {2015}
}

Comments

article, 9 pages, revised

R2 v1 2026-06-22T04:52:34.855Z