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We consider a system of particles confined in a box $\La\subset\R^d$ interacting via a tempered and stable pair potential. We prove the validity of the cluster expansion for the canonical partition function in the high temperature - low…

Mathematical Physics · Physics 2015-05-28 Elena Pulvirenti , Dimitrios Tsagkarogiannis

A well-known cluster expansion, which leads to virial expansion for the free energy of low density systems, is modified in such a way that it becomes applicable to the description of condensed state of matter. To this end, the averaging of…

Statistical Mechanics · Physics 2018-12-21 G. S. Bokun , M. F. Holovko

Mayer cluster expansion is an important tool in statistical physics to evaluate grand canonical partition functions. It has recently been applied to the Nekrasov instanton partition function of $\mathcal{N}=2$ 4d gauge theories. The…

High Energy Physics - Theory · Physics 2014-02-04 Jean-Emile Bourgine

On the example of a lattice-gas model, a convincing confirmation is obtained for the direct relationship between the condensation phenomenon and divergent behavior of the virial expansions for pressure and density in powers of activity. The…

Statistical Mechanics · Physics 2018-10-24 Michael V. Ushcats , Leonid A. Bulavin

We perform a cluster expansion in the canonical ensemble with periodic boundary conditions, introducing a new choice of polymer activities that differs from the standard ones. This choice leads to an improved bound for the convergence of…

Mathematical Physics · Physics 2026-03-27 Giuseppe Scola

A method is proposed to approximate the unlimited subcritical set of Mayer`s reducible cluster integrals (i.e., the power coefficients of the known virial expansions for pressure and density in powers of activity) on the basis of…

Chemical Physics · Physics 2020-03-05 M. V. Ushcats , L. A. Bulavin

A univariate clustering criterion for stationary processes satisfying a $\beta$-mixing condition is proposed extending the work of \cite{KB2} to the dependent setup. The approach is characterized by an alternative sample criterion function…

Statistics Theory · Mathematics 2013-11-19 Karthik Bharath

The virial expansion method is applied within a harmonic approximation to an interacting N-body system of identical fermions. We compute the canonical partition functions for two and three particles to get the two lowest orders in the…

Statistical Mechanics · Physics 2012-12-27 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

McMillan and Mayer (MM) proved two remarkable theorems in their paper on the equilibrium statistical mechanics of liquid solutions. They first showed that the grand canonical partition function for a solution can be reduced to a one with an…

Chemical Physics · Physics 2015-06-19 Shaghayegh Vafaei , Bruno Tomberli , C. G. Gray

Using schematic model potentials, we calculate exactly the virial coefficients of a classical gas up to sixth order and use them to assess the convergence properties of the virial expansion of basic thermodynamic quantities such as…

Computational Physics · Physics 2023-07-26 Aaron M. Miller , Joaquín E. Drut

We develop the cluster expansion and the Mayer expansion for the self-gravitating thermal gas and prove the existence and stability of the thermodynamic limit N, V to infty with N/V^{1/3} fixed. The essential (dimensionless) variable is…

Astrophysics · Physics 2009-11-10 H. J. de Vega , N. Sanchez

We investigate the kinetics of constant-kernel aggregation which is augmented by either: (a) evaporation of monomers from finite-mass clusters, or (b) continuous cluster growth -- \ie, condensation. The rate equations for these two…

Condensed Matter · Physics 2009-10-28 Paul. L. Krapivsky , Sidney Redner

We study the convergence of cluster and virial expansions for systems of particles subject to positive two-body interactions. Our results strengthen and generalize existing lower bounds on the radii of convergence and on the value of the…

Mathematical Physics · Physics 2019-10-01 Roberto Fernández , Nguyen Tong Xuan

We study the virial expansion of mixtures of countably many different types of particles. The main tool is the Lagrange-Good inversion formula, which has other applications such as counting coloured trees or studying probability generating…

Mathematical Physics · Physics 2014-06-24 Sabine Jansen , Stephen J. Tate , Dimitrios Tsagkarogiannis , Daniel Ueltschi

We consider N particles interacting pair-wise by an inverse square potential in one dimension (Calogero-Sutherland-Moser model). When trapped harmonically, its classical canonical partition function for the repulsive regime is known in the…

Statistical Mechanics · Physics 2015-05-14 R. K. Bhaduri , M. V. N. Murthy , Diptiman Sen

An interesting problem in statistical physics is the condensation of classical particles in droplets or clusters when the pair-interaction is given by a stable Lennard-Jones-type potential. We study two aspects of this problem. We start by…

Probability · Mathematics 2015-03-18 Sabine Jansen , Wolfgang König , Bernd Metzger

The cluster cumulant formula of Kubo is derived by appealing only to elementary properties of subsets and binomial coefficients. It is shown to be a binomial transform of the grand potential. Extensivity is proven without introducing…

Statistical Mechanics · Physics 2007-05-23 D. K. Sunko

The study of Mayer's cluster expansion (CE) for the partition function demonstrates a possible way to resolve the problem of the CE non-physical behavior at condensed states of fluids. In particular, a general equation of state is derived…

Statistical Mechanics · Physics 2018-10-03 M. V. Ushcats , S. Yu. Ushcats , L. A. Bulavin , V. M. Sysoev

The formation, inner properties, and spatial distribution of galaxy groups and clusters are closely related to the background cosmological model. We use numerical simulations of variants of the CDM model with different cosmological…

Astrophysics · Physics 2011-05-23 Alexander Knebe , Volker Mueller

We employ the $\Phi-$ derivable approach to many particle systems with strong correlations that can lead to the formation of bound states (clusters) of different size. We define a generic form of $\Phi-$ functionals that is fully equivalent…

Nuclear Theory · Physics 2015-02-24 David Blaschke
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