V-V Bond-Length Fluctuations in Vox
Abstract
We report a significantly stronger suppression of the phonon contribution to the thermal conductivity in VOx than can be accounted for by disorder of the 16 % atomic vacancies present in VO. Since the transition from localized to itinerant electronic behavior is first-order and has been shown to be characterized by bond-length fluctuations in several transition-metal oxides with the perovskite structure, we propose that cooperative V-V bond-length fluctuations play a role in VO similar to the M-O bond-length fluctuations in the perovskites. This model is able to account for the strong suppression of the thermal conductivity, the existence of a pseudogap confirmed by thermoelectric power, an anomalously large Debye-Waller factor, the temperature dependence of the magnetic susceptibility, and the inability to order atomic vacancies in VO.
Keywords
Cite
@article{arxiv.cond-mat/0211208,
title = {V-V Bond-Length Fluctuations in Vox},
author = {J. B. Goodenough and F. Rivadulla and E. Winkler and J. -S. Zhou},
journal= {arXiv preprint arXiv:cond-mat/0211208},
year = {2009}
}
Comments
5 pages, 5 figures