Photo-induced insulator-metal transition in VO2 and the related transient and multi-timescale structural dynamics upon photoexcitation are explained within a unified framework. Holes created by photoexcitation weaken the V-V bonds and eventually break V-V dimers in the M1 phase of VO2 when the laser fluence reaches a critical value. The breaking of the V-V bonds in turn leads to an immediate electronic phase transition from an insulating to a metallic state while the crystal lattice remains monoclinic in shape. The coupling between excited electrons and the 6.0 THz phonon mode is found to be responsible for the observed zig-zag motion of V atoms upon photoexcitation and is consistent with coherent phonon experiments.
@article{arxiv.1301.6215,
title = {Hole-lattice Coupling and Photo-induced Insulator-Metal Transition in VO$_2$},
author = {Xun Yuan and Wenqing Zhang and Peihong Zhang},
journal= {arXiv preprint arXiv:1301.6215},
year = {2013}
}