English

Tuning the magnetic interactions in van der Waals Fe$_3$GeTe$_2$ heterostructures: A comparative study of \textit{ab initio} methods

Materials Science 2023-03-30 v2

Abstract

We investigate the impact of mechanical strain, stacking order, and external electric fields on the magnetic interactions of a two-dimensional (2D) van der Waals (vdW) heterostructure in which a 2D ferromagnetic metallic Fe3_3GeTe2_2 monolayer is deposited on germanene. Three distinct computational approaches based on \textit{ab initio} methods are used, and a careful comparison is given: (i) The Green's function method, (ii) the generalized Bloch theorem, and (iii) the supercell approach. First, the shell-resolved exchange constants are calculated for the three Fe atoms within the unit cell of the freestanding Fe3_3GeTe2_2 monolayer. We find that the results between methods (i) and (ii) are in good qualitative agreement and also with previously reported values. An electric field of E=±0.5{\cal E}= \pm 0.5~V/{\AA} applied perpendicular to the Fe3_3GeTe2_2/germanene heterostructure leads to significant changes of the exchange constants. We show that the Dzyaloshinskii-Moriya interaction (DMI) in Fe3_3GeTe2_2/germanene is mainly dominated by the nearest neighbors, resulting in a good quantitative agreement between methods (i) and (ii). Furthermore, we demonstrate that the DMI is highly tunable by strain, stacking, and electric field, leading to a large DMI comparable to that of ferromagnetic/heavy metal (FM/HM) interfaces. The geometrical change and hybridization effect explain the origin of the high tunability of the DMI at the interface. The electric-field driven DMI obtained by method (iii) is in qualitative agreement with the more accurate \textit{ab initio} method used in approach (ii). However, the field-effect on the DMI is overestimated by method (iii) by about 50\%. The magnetocrystalline anisotropy energy can also be drastically changed by the application of compressive or tensile strain in the Fe3_3GeTe2_2/germanene heterostructure.

Keywords

Cite

@article{arxiv.2210.15351,
  title  = {Tuning the magnetic interactions in van der Waals Fe$_3$GeTe$_2$ heterostructures: A comparative study of \textit{ab initio} methods},
  author = {Dongzhe Li and Soumyajyoti Haldar and Tim Drevelow and Stefan Heinze},
  journal= {arXiv preprint arXiv:2210.15351},
  year   = {2023}
}

Comments

15 pages, 12 figures