English

The stable behavior of low thermal conductivity in 1T-sandwich structure with different components

Materials Science 2024-06-19 v1 Chemical Physics Computational Physics

Abstract

Designing materials with low thermal conductivity (\k{appa}) is of demand for thermal protection, heat insulation, thermoelectricity, etc. In this paper, based on the start-of-art first-principles calculations, we propose a framework of a 1T-sandwich structure for designing materials with low \k{appa}. The 1T-sandwich structure is the same as the well-known transition metal dichalcogenide (TMD) but with light Carbon atoms in the middle plane. Using different atoms to fill the outer positions, a few novel two-dimensional materials are constructed as study cases, i.e., Mg2C, Janus MgBeC, Be2C, and Mo2C. With a systematic and comparative study, the \k{appa} are calculated to be 3.74, 8.26, 14.80, 5.13 W/mK, respectively. The consistent values indicate the stable behavior of low \k{appa} in the 1T-sandwich structure, being insensitive to the component. Our study would help design advanced functional materials with reliable heat transfer performance for practical applications, which reduces the influence of unavoidable impurities.

Keywords

Cite

@article{arxiv.2202.07343,
  title  = {The stable behavior of low thermal conductivity in 1T-sandwich structure with different components},
  author = {E Zhou and Jing Wu and Chen Shen and Hongbin Zhang and Guangzhao Qin},
  journal= {arXiv preprint arXiv:2202.07343},
  year   = {2024}
}