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The retarded van der Waals potential - revisited

Mathematical Physics 2009-01-26 v1 math.MP

Abstract

The retarded van-der-Waals potential, as first obtained by Casimir and Polder, is usually computed on the basis of nonrelativistic QED. The hamiltonian describes two infinitely heavy nuclei, charge ee, separated by a distance RR and two spinless electrons, charge e-e, nonrelativistically coupled to the quantized radiation field. Casimir and Polder use the dipole approximation and small coupling to the Maxwell field. We employ here the full hamiltonian and determine the asymptotic strength of the leading R7-R^{-7} potential, which is valid for all ee. Our computation is based on a path integral representation and expands in 1/R1/R, rather than in ee.

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Cite

@article{arxiv.0901.3678,
  title  = {The retarded van der Waals potential - revisited},
  author = {Tadahiro Miyao and Herbert Spohn},
  journal= {arXiv preprint arXiv:0901.3678},
  year   = {2009}
}

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26 pages