English

The characteristics of LK-99 by Cu$_2$S removal using ammonia solution: A diamagnetic semiconductor

Materials Science 2023-10-02 v1

Abstract

In this study, we re-evaluated the superconducting properties of LK-99. The LK-99 samples were synthesized using the process proposed by the original Korean team. Additionally, we examined whether the results of the Korean team are related to Cu2_2S by using ammonia solution (NH3_3-H2_2O) to remove Cu2_2S . Through x-ray diffraction (XRD) analysis, a distinct Cu2_2S phase was identified in the LK-99 samples. A subsequent treatment using an ammonia solution effectively eliminated this phase. The appearance of blue Cu+2^{+2} ions in the solution and the elimination of the Cu2_2S peak in XRD support the conclusion. The magnetic and electrical properties of LK-99 with and without Cu2_2S postulate that the superconducting-like behavior in LK-99 predominantly arises from a transition in resistivity due to the influence of Cu2_2S . As such, LK-99 is better classified as a diamagnetic semiconductor than a room-temperature superconductor. The room-temperature superconductors still require further research.

Keywords

Cite

@article{arxiv.2309.17445,
  title  = {The characteristics of LK-99 by Cu$_2$S removal using ammonia solution: A diamagnetic semiconductor},
  author = {Zhujialei Lei and Chin-Wei Lin and I-Nan Chen and Chun-Tse Chou and Li-Min Wang},
  journal= {arXiv preprint arXiv:2309.17445},
  year   = {2023}
}