Tapered ultra-high Numerical Aperture optical fiber tip for Nitrogen Vacancy ensembles based endoscope in a fluidic environment

Fixing a diamond containing a high density of Nitrogen-Vacancy (NV) center ensembles on the apex of a multimode optical fiber (MMF) extends the applications of NV-based endoscope sensors. Replacing the normal MMF with a tapered MMF (MMF-taper) has enhanced the fluorescence (FL) collection efficiency from the diamond and achieved a high spatial resolution NV-based endoscope. The MMF-taper's high FL collection efficiency is the direct result of multiple internal reflections in the tapered region caused by silica, which has a higher refractive index (RI) than the surrounding air. However, for applications involving fluidic environments whose RI is close to or higher than that of the silica, the MMF-taper loses its FL collection significantly. Here, to overcome this challenge, we replaced the MMF-taper with an ultra-high numerical aperture (NA) microstructured optical fiber (MOF) which is tapered and sealed its air capillaries at the tapered end. Since the end-sealed air capillaries along the tapered MOF (MOF-taper) have isolated the MOF core from the surrounding medium, the core retains its high FL collection and NV excitation efficiency in liquids regardless of their RI values. Such a versatile NV-based endoscope could potentially find broad applications in fluidic environments where many biological processes and chemical reactions occur.