We report a new family of chiral intermetallic superconductors TaAlxGe2−x. The mother compound TaGe2 has a C40-type chiral hexagonal crystal structure with a pair of enantiomorphic space groups of P6222 and P6422. By substituting Ge with Al, TaAlxGe2−x polycrystals with the C40 structure were synthesized with Al substitution x from 0 to 0.8. Magnetic susceptibility, magnetization curves and electrical resistivity revealed that TaAlxGe2−x with x of 0.2 to 0.4 was a type-II superconductor with a superconducting transition temperature Tc of 2.0 to 2.2 K. The superconductivity disappeared or was largely suppressed at x less than 0.2 and more than 0.4, although all the measurements were performed at temperatures above 1.8 K. An emergence of superconductivity is discussed in terms of the lattice constants changes with the Al substitution.
@article{arxiv.2411.14549,
title = {Superconductivity in Ternary Germanite TaAl$_{x}$Ge$_{2-x}$ with a C40 chiral structure},
author = {Daigo Koizumi and Shingo Kisanuki and Kenta Monden and Yusuke Kousaka and Hiroaki Shishido and Yoshihiko Togawa},
journal= {arXiv preprint arXiv:2411.14549},
year = {2024}
}