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Superconductivity in Ternary Germanite TaAl$_{x}$Ge$_{2-x}$ with a C40 chiral structure

Superconductivity 2024-11-25 v1 Materials Science

Abstract

We report a new family of chiral intermetallic superconductors TaAlx_{x}Ge2x_{2-x}. The mother compound TaGe2_2 has a C40-type chiral hexagonal crystal structure with a pair of enantiomorphic space groups of P6222P6{_2}22 and P6422P6{_4}22. By substituting Ge with Al, TaAlx_{x}Ge2x_{2-x} polycrystals with the C40 structure were synthesized with Al substitution xx from 0 to 0.8. Magnetic susceptibility, magnetization curves and electrical resistivity revealed that TaAlx_{x}Ge2x_{2-x} with xx of 0.2 to 0.4 was a type-II superconductor with a superconducting transition temperature TcT_{\rm c} of 2.0 to 2.2 K. The superconductivity disappeared or was largely suppressed at xx less than 0.2 and more than 0.4, although all the measurements were performed at temperatures above 1.8 K. An emergence of superconductivity is discussed in terms of the lattice constants changes with the Al substitution.

Keywords

Cite

@article{arxiv.2411.14549,
  title  = {Superconductivity in Ternary Germanite TaAl$_{x}$Ge$_{2-x}$ with a C40 chiral structure},
  author = {Daigo Koizumi and Shingo Kisanuki and Kenta Monden and Yusuke Kousaka and Hiroaki Shishido and Yoshihiko Togawa},
  journal= {arXiv preprint arXiv:2411.14549},
  year   = {2024}
}

Comments

7 pages, 7 figures