This article reports the structural and magnetic characterisation of a new hexagonal (P63cm) low-temperature phase of Ba3Tb(BO3)3, isostructural with the heavier lanthanide borates with formula Ba3Ln(BO3)3 (Ln = Dy-Lu). The crystal structure contains a quasi-two-dimensional (2D) triangular lattice of Tb3+ ions and is predicted to display unusual magnetic behaviour as a result of the low dimensionality. Magnetic susceptibility χ(T) shows antiferromagnetic interactions (θCW=−7.15 K) and no sharp ordering transition at T≥2 K, but analysis of χ′(T), isothermal magnetisation and heat capacity suggests the possibility of short-range ordering at T≈10 K. The material exhibits an inverse magnetocaloric effect at T<4 K.
@article{arxiv.2007.15453,
title = {Structure and magnetism of a new hexagonal polymorph of Ba$_3$Tb(BO$_3$)$_3$ with a quasi-2D triangular lattice},
author = {Nicola Kelly and Cheng Liu and Siân Dutton},
journal= {arXiv preprint arXiv:2007.15453},
year = {2020}
}