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Stripes in oxygen-enriched cuprates

General Physics 2020-12-04 v2

Abstract

Charge-order stripes of different types occur when copper oxides are doped with either heterovalent metal, like La2xSrxCuO4La_{2-x}Sr_xCuO_4, or oxygen, like YBa2Cu3O6+yYBa_2Cu_3O_{6+y}. The difference shows up in the doping dependence of their incommensurability: qc(x)xpˇq_c(x) \propto \sqrt{x-\check{p}} but qc(y)0.3q_c(y) \approx 0.3. The square-root dependence in the former compound family results from Coulomb repulsion between doped holes (or electrons), residing pairwise in lattice-site OO (or CuCu) atoms of the CuO2CuO_2 planes. The almost constant qc(y)q_c(y) value in the second family results from the aggregation of ozone-like molecules, formed from O2O^{2-} ions of the host with embedded oxygen atoms, OiO_i, at interstitial sites in the CuO2CuO_2 planes. The magnetic moments, m(O)\mathbf{m}(O), of the lattice-defect OO atoms in the first family arrange antiferromagnetically, which gives rise to accompanying magnetization stripes of incommensurability qm(x)=qc(x)/2q_m(x) = q_c(x)/2. The ozone complexes have a vanishing magnetic moment, m=0\mathbf{m}=0, which explains the absence of accompanying magnetization stripes in the second family. Embedding excess oxygen as OiO_i atoms in CuO2CuO_2 planes is likewise assumed for HgBa2CuO4+δHgBa_2CuO_{4+\delta} and oxygen-enriched bismuth cuprates. A combination of characteristics from both families is present in oxygen-enriched La2CuO4+yLa_2CuO_{4+y}. The validity of determining the hole density in oxygen-enriched cuprates with the universal-dome method is independently confirmed. Besides causing different types of stripes, the two types of lattice-defect oxygen may also cause different types of superconductivity. This could explain the much higher Tc,maxT_{c,max} in oxygen-enriched than SrSr-doped cuprates, as well as the cusped cooling-curves of X-ray intensity diffracted by stripes in the former family.

Keywords

Cite

@article{arxiv.2010.06388,
  title  = {Stripes in oxygen-enriched cuprates},
  author = {Manfred Bucher},
  journal= {arXiv preprint arXiv:2010.06388},
  year   = {2020}
}

Comments

43 pages, 10 figures, 6 tables. In version 2, previous typographic errors are corrected and minor improvements are implemented

R2 v1 2026-06-23T19:18:40.710Z