Stripes in oxygen-enriched cuprates
Abstract
Charge-order stripes of different types occur when copper oxides are doped with either heterovalent metal, like , or oxygen, like . The difference shows up in the doping dependence of their incommensurability: but . The square-root dependence in the former compound family results from Coulomb repulsion between doped holes (or electrons), residing pairwise in lattice-site (or ) atoms of the planes. The almost constant value in the second family results from the aggregation of ozone-like molecules, formed from ions of the host with embedded oxygen atoms, , at interstitial sites in the planes. The magnetic moments, , of the lattice-defect atoms in the first family arrange antiferromagnetically, which gives rise to accompanying magnetization stripes of incommensurability . The ozone complexes have a vanishing magnetic moment, , which explains the absence of accompanying magnetization stripes in the second family. Embedding excess oxygen as atoms in planes is likewise assumed for and oxygen-enriched bismuth cuprates. A combination of characteristics from both families is present in oxygen-enriched . The validity of determining the hole density in oxygen-enriched cuprates with the universal-dome method is independently confirmed. Besides causing different types of stripes, the two types of lattice-defect oxygen may also cause different types of superconductivity. This could explain the much higher in oxygen-enriched than -doped cuprates, as well as the cusped cooling-curves of X-ray intensity diffracted by stripes in the former family.
Keywords
Cite
@article{arxiv.2010.06388,
title = {Stripes in oxygen-enriched cuprates},
author = {Manfred Bucher},
journal= {arXiv preprint arXiv:2010.06388},
year = {2020}
}
Comments
43 pages, 10 figures, 6 tables. In version 2, previous typographic errors are corrected and minor improvements are implemented