Strictly Non-Adiabatic Quantum Control of the Acetylene Dication Using an Infrared Field
Chemical Physics
2020-05-20 v1 Quantum Physics
Abstract
We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a TDSE simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics.
Keywords
Cite
@article{arxiv.2003.02096,
title = {Strictly Non-Adiabatic Quantum Control of the Acetylene Dication Using an Infrared Field},
author = {Chelsea Liekhus-Schmaltz and Xiaolei Zhu and Gregory A. McCracken and James P. Cryan and Todd Martinez and Philip H. Bucksbaum},
journal= {arXiv preprint arXiv:2003.02096},
year = {2020}
}
Comments
7 pages, 3 figures