English

Steering alkyne homocoupling with on-surface synthesized catalysts

Materials Science 2020-06-24 v1
Authors: Mohammed S. G. Mohammed , Luciano Colazzo , Aurelio Gallardo , José A. Pomposo , Pavel Jelínek , Dimas G. de Oteyza
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Abstract

We report a multi-step on-surface synthesis strategy. The first step consists in the surface-supported synthesis of metal-organic complexes, which are subsequently used as catalysts to steer on-surface alkyne coupling reactions. In addition, we analyze and compare the electronic properties of the different coupling motifs obtained.

Keywords

on-surface synthesis metal-organic complexes alkyne homocoupling catalysis electronic properties coupling motifs

Cite

@article{arxiv.2006.12818,
  title  = {Steering alkyne homocoupling with on-surface synthesized catalysts},
  author = {Mohammed S. G. Mohammed and Luciano Colazzo and Aurelio Gallardo and José A. Pomposo and Pavel Jelínek and Dimas G. de Oteyza},
  journal= {arXiv preprint arXiv:2006.12818},
  year   = {2020}
}

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