English

Surface-Directed Spinodal Decomposition on Chemically Patterned Substrates

Soft Condensed Matter 2020-07-20 v1 Statistical Mechanics

Abstract

{\it Surface-directed spinodal decomposition} (SDSD) is the kinetic interplay of phase separation and wetting at a surface. This process is of great scientific and technological importance. In this paper, we report results from a numerical study of SDSD on a chemically patterned substrate. We consider simple surface patterns for our simulations, but most of the results apply for arbitrary patterns. In layers near the surface, we observe a dynamical crossover from a {\it surface-registry regime} to a {\it phase-separation regime}. We study this crossover using layer-wise correlation functions and structure factors, and domain length scales.

Keywords

Cite

@article{arxiv.2006.12232,
  title  = {Surface-Directed Spinodal Decomposition on Chemically Patterned Substrates},
  author = {Prasenjit Das and Prabhat K. Jaiswal and Sanjay Puri},
  journal= {arXiv preprint arXiv:2006.12232},
  year   = {2020}
}

Comments

19 Pages, 11 Figs, Accepted to Physical Review E

R2 v1 2026-06-23T16:31:09.606Z