English

Solving stochastic chemical kinetics by Metropolis Hastings sampling

Numerical Analysis 2014-10-31 v1

Abstract

This study considers using Metropolis-Hastings algorithm for stochastic simulation of chemical reactions. The proposed method uses SSA (Stochastic Simulation Algorithm) distribution which is a standard method for solving well-stirred chemically reacting systems as a desired distribution. A new numerical solvers based on exponential form of exact and approximate solutions of CME (Chemical Master Equation) is employed for obtaining target and proposal distributions in Metropolis-Hastings algorithm to accelerate the accuracy of the tau-leap method. Samples generated by this technique have the same distribution as SSA and the histogram of samples show it's convergence to SSA.

Keywords

Cite

@article{arxiv.1410.8155,
  title  = {Solving stochastic chemical kinetics by Metropolis Hastings sampling},
  author = {Azam S. Zavar Moosavi and Paul Tranquilli and Adrian Sandu},
  journal= {arXiv preprint arXiv:1410.8155},
  year   = {2014}
}
R2 v1 2026-06-22T06:40:56.774Z