English

Smectic-like rheology and pseudo-layer compression elastic constant of a twist-bend nematic liquid crystal

Soft Condensed Matter 2020-11-25 v2

Abstract

In twist-bend nematic (N\textsubscript{TB}) liquid crystals (LCs), the mean molecular orientation exhibits heliconical structure with nanoscale periodicity. On the mesoscopic scale, N\textsubscript{TB} resembles layered systems (like smectics), where the helical pitch is equivalent to "pseudo-layers" without a true mass density wave. We study rheological properties of a N\textsubscript{TB} phase and compare the results with those of an usual SmA phase. Analysing the shear response and adapting a simplified physical model for rheology of defect mediated lamellar systems we measure the pseudo-layer compression elastic constant BeffB_{eff} of N\textsubscript{TB} phase from the measurements of dynamic modulus G(ω)G^{*}(\omega). We find that BeffB_{eff} of the N\textsubscript{TB} phase is in the range of 10310610^{3}-10^{6} Pa and it follows a temperature dependence, Beff(TTBT)2B_{eff}\sim (T_{TB}-T)^{2} as predicted by the recent coarse-grained elastic theory. Our results show that the structural rheology of N\textsubscript{TB} is strikingly similar to that of the usual smectic LCs although the temperature dependence of BeffB_{eff} is much faster than smectic LCs as predicted by the coarse-grained models.

Keywords

Cite

@article{arxiv.2008.10228,
  title  = {Smectic-like rheology and pseudo-layer compression elastic constant of a twist-bend nematic liquid crystal},
  author = {M. Praveen Kumar and P. Kula and Surajit Dhara},
  journal= {arXiv preprint arXiv:2008.10228},
  year   = {2020}
}

Comments

6 pages, 6 figures