Singular Hylleraas three-electron integrals
Atomic Physics
2009-11-13 v1 Chemical Physics
Abstract
Calculations of the leading quantum electrodynamics effects in few electron systems involve singular matrix elements of the inter-electronic distances of the form and . Integrals that result when the nonrelativistic wave function is represented with a Hylleraas basis representation are studied. Recursion relations for various powers of the electron coordinates and the master integrals are derived in a form suited for high precision numerical evaluations.
Keywords
Cite
@article{arxiv.0803.0801,
title = {Singular Hylleraas three-electron integrals},
author = {Krzysztof Pachucki and Mariusz Puchalski},
journal= {arXiv preprint arXiv:0803.0801},
year = {2009}
}
Comments
20 pages, accepted for Phys. Rev. A