English

Singular Hylleraas three-electron integrals

Atomic Physics 2009-11-13 v1 Chemical Physics

Abstract

Calculations of the leading quantum electrodynamics effects in few electron systems involve singular matrix elements of the inter-electronic distances of the form 1/ri31/r_i^3 and 1/rij31/r_{ij}^3. Integrals that result when the nonrelativistic wave function is represented with a Hylleraas basis representation are studied. Recursion relations for various powers of the electron coordinates and the master integrals are derived in a form suited for high precision numerical evaluations.

Keywords

Cite

@article{arxiv.0803.0801,
  title  = {Singular Hylleraas three-electron integrals},
  author = {Krzysztof Pachucki and Mariusz Puchalski},
  journal= {arXiv preprint arXiv:0803.0801},
  year   = {2009}
}

Comments

20 pages, accepted for Phys. Rev. A

R2 v1 2026-06-21T10:18:54.996Z