English

Single crystal growth and characterization of antiferromagnetically ordering EuIn$_2$

Materials Science 2023-08-08 v1

Abstract

We report the single crystal growth and characterization of EuIn2_2, a magnetic topological semimetal candidate according to our density functional theory (DFT) calculations. We present results from electrical resistance, magnetization, M\"ossbauer spectroscopy, and X-ray resonant magnetic scattering (XRMS) measurements. We observe three magnetic transitions at TN114.2 T_{\text{N}1}\sim 14.2~K, TN212.8 T_{\text{N}2}\sim12.8~K and TN311 T_{\text{N}3}\sim 11~K, signatures of which are consistently seen in anisotropic temperature dependent magnetic susceptibility and electrical resistance data. M\"ossbauer spectroscopy measurements on ground crystals suggest an incommensurate sinusoidally modulated magnetic structure below the transition at TN114 T_{\text{N}1}\sim 14~K, followed by the appearance of higher harmonics in the modulation on further cooling roughly below TN213 T_{\text{N}2}\sim13~K, before the moment distribution squaring up below the lowest transition around TN311 T_{\text{N}3}\sim 11~K. XRMS measurements showed the appearance of magnetic Bragg peaks below TN114 T_{\text{N}1}\sim14~K, with a propagation vector of τ\bm{\tau} =(τh,τˉh,0)=(\tau_h,\bar{\tau}_h,0), with τh\tau_hvarying with temperature, and showing a jump at TN311T_{\text{N}3}\sim11~K. The temperature dependence of τh\tau_h between 11\sim11~K and 1414~K shows incommensurate values consistent with the M\"{o}ssbauer data. XRMS data indicate that τh\tau_h remains incommensurate at low temperatures and locks into τh=0.3443(1)\tau_h=0.3443(1).

Keywords

Cite

@article{arxiv.2308.03600,
  title  = {Single crystal growth and characterization of antiferromagnetically ordering EuIn$_2$},
  author = {Brinda Kuthanazhi and Simon X. M. Riberolles and Dominic H. Ryan and Philip J. Ryan and Jong-Woo Kim and Lin-Lin Wang and Robert J. McQueeney and Benjamin G. Ueland and Paul C. Canfield},
  journal= {arXiv preprint arXiv:2308.03600},
  year   = {2023}
}