English

Signatures of dynamic heterogeneity from a generalized hydrodynamic model of the supercooled liquid

Statistical Mechanics 2014-02-17 v1

Abstract

In this paper we study the four point correlation function χ4\chi_4 of collective density fluctuations in a nonequilibrium liquid. The equilibration is controlled by a modified stretched exponential behavior ( exp[(tw/τ)β]\exp [-{(t_\mathrm{w}/\tau)}^\beta] ) having the relaxation time τ\tau dependent on the aging time twt_\mathrm{w}. Similar aging behavior has been seen experimentally in supercooled liquids. The basic equations of fluctuating nonlinear hydrodynamics (FNH) are solved here numerically to obtain χ4\chi_4 for equilibrium and non equilibrium states. We also identify a dynamic length scale ξ\xi from the equilibrated function. ξ(T)\xi(T) grows with fall of temperature TT. From a broader perspective, we demonstrate here that the characteristic signatures of dynamical heterogeneities in a supercooled liquid, observed previously in computer simulations of the dynamics of a small number of particles, are also present in the coarse grained equations of generalized hydrodynamics.

Keywords

Cite

@article{arxiv.1402.3404,
  title  = {Signatures of dynamic heterogeneity from a generalized hydrodynamic model of the supercooled liquid},
  author = {Bhaskar Sen Gupta and Shankar P. Das},
  journal= {arXiv preprint arXiv:1402.3404},
  year   = {2014}
}

Comments

6 figures