English

Shannon entropy: a study of confined hydrogenic-like atoms

Atomic Physics 2017-11-28 v2

Abstract

The Shannon entropy in the atomic, molecular and chemical physics context is presented by using as test cases the hydrogenic-like atoms HcH_c, Hec+{He_c}^+ and Lic2+{Li_c}^{2+} confined by an impenetrable spherical box. Novel expressions for entropic uncertainty relation and Shannon entropies SrS_r and SpS_p are proposed to ensure their physical dimensionless characteristic. The electronic ground state energy and the quantities SrS_r, SpS_p and StS_t are calculated for the hydrogenic-like atoms to different confinement radii by using a variational method. The global behavior of these quantities and different conjectures are analyzed. The results are compared, when available, with those previously published.

Keywords

Cite

@article{arxiv.1704.04874,
  title  = {Shannon entropy: a study of confined hydrogenic-like atoms},
  author = {Wallas S. Nascimento and Frederico V. Prudente},
  journal= {arXiv preprint arXiv:1704.04874},
  year   = {2017}
}

Comments

Version accepted for publication in Chemical Physics Letters