English

Self-diffusion anomalies of an odd tracer in soft-core media

Statistical Mechanics 2024-11-26 v1 Biological Physics

Abstract

Odd-diffusive systems, characterised by broken time-reversal and/or parity symmetry, have recently been shown to display counterintuitive features such as interaction-enhanced dynamics in the dilute limit. Here we we extend the investigation to the high-density limit of an odd tracer embedded in a soft-Gaussian core medium (GCM) using a field-theoretic approach based on the Dean-Kawasaki equation. Our theory reveals that interactions can enhance the dynamics of an odd tracer even in dense systems. We demonstrate that oddness results in a complete reversal of the well-known self-diffusion (DsD_\mathrm{s}) anomaly of the GCM. Ordinarily, DsD_\mathrm{s} exhibits a non-monotonic trend with increasing density, approaching but remaining below the interaction-free diffusion, D0D_0, (Ds<D0D_\mathrm{s} < D_0) so that DsD0D_\mathrm{s} \uparrow D_0 at high densities. In contrast, for an odd tracer, self-diffusion is enhanced (Ds>D0D_\mathrm{s}> D_0) and the GCM anomaly is inverted, displaying DsD0D_\mathrm{s} \downarrow D_0 at high densities. The transition between the standard and reversed GCM anomaly is governed by the tracer's oddness, with a critical oddness value at which the tracer diffuses as a free particle (DsD0D_\mathrm{s} \approx D_0) across all densities. We validate our theoretical predictions with Brownian dynamics simulations, finding strong agreement between the two.

Keywords

Cite

@article{arxiv.2411.15552,
  title  = {Self-diffusion anomalies of an odd tracer in soft-core media},
  author = {Pietro Luigi Muzzeddu and Erik Kalz and Andrea Gambassi and Abhinav Sharma and Ralf Metzler},
  journal= {arXiv preprint arXiv:2411.15552},
  year   = {2024}
}

Comments

26 pages, 3 figures, IOPLaTeX