English

Selective reflection of light in glassforming ternary liquid crystalline mixtures

Soft Condensed Matter 2026-05-08 v2

Abstract

Two ternary liquid crystalline mixtures are formulated and investigated by differential scanning calorimetry, polarizing optical microscopy, X-ray diffraction, and broadband dielectric spectroscopy. Paraelectric smectic A*, ferroelectric smectic C*, and antiferroelectric smectic CA_A* phases are detected. The glass of the smectic CA_A* phase is formed at moderate cooling rates. Vitrification prevents the approaching transition to a hexatic smectic phase. One mixture shows a strong thermochromic effect in the smectic CA_A* phase and selectively reflects blue light in the glassy state. Both mixtures reflect either green or red light in the smectic C* phase, depending on temperature treatment: whether the sample is cooled or heated, or at which rate the temperature changes.

Keywords

Cite

@article{arxiv.2509.17633,
  title  = {Selective reflection of light in glassforming ternary liquid crystalline mixtures},
  author = {Aleksandra Deptuch and Zuzanna Zając and Marcin Piwowarczyk and Anna Drzewicz and Marcin Kozieł and Magdalena Urbańska and Ewa Juszyńska-Gałązka},
  journal= {arXiv preprint arXiv:2509.17633},
  year   = {2026}
}

Comments

one co-author added, experimental results extended by X-ray diffraction measurements as a function of temperature