Rotational transitions of iso-propyl cyanide, (CH3)2CHCN, also known as iso-butyronitrile, were recorded using long-path absorption spectroscopy in selected regions between 37 and 600 GHz. Further measurements were carried out between 6 and 20 GHz employing Fourier transform microwave (FTMW) spectroscopy on a pulsed molecular supersonic jet. The observed transitions reach J and Ka quantum numbers of 103 and 59, respectively, and yield accurate rotational constants as well as distortion parameters up to eighth order. The 14N nuclear hyperfine splitting was resolved in particular by FTMW spectroscopy yielding spin-rotation parameters as well as very accurate quadrupole coupling terms. In addition, Stark effect measurements were carried out in the microwave region to obtain a largely revised c-dipole moment component and to improve the a-component. The hyperfine coupling and dipole moment values are compared with values for related molecules both from experiment and from quantum chemical calculations.
@article{arxiv.1102.5675,
title = {Rotational spectroscopy, dipole moment and $^{14}$N nuclear hyperfine structure of $iso$-propyl cyanide},
author = {Holger S. P. Müller and Audrey Coutens and Adam Walters and Jens-Uwe Grabow and Stephan Schlemmer},
journal= {arXiv preprint arXiv:1102.5675},
year = {2019}
}