English

Precise dipole moment and quadrupole coupling constants of benzonitrile

Chemical Physics 2007-12-21 v2

Abstract

We have performed Fourier transform microwave spectroscopy of benzonitrile, without and with applied electric fields. From the field-free hyperfine-resolved microwave transitions we simultaneously derive accurate values for the rotational constants, centrifugal distortion constants, and nitrogen nuclear quadrupole coupling constants of benzonitrile. By measuring the Stark shift of selected hyperfine transitions the electric dipole moment of benzonitrile is determined to μ=μa=4.5152(68)\mu=\mu_a=4.5152 (68) D.

Keywords

Cite

@article{arxiv.0709.2984,
  title  = {Precise dipole moment and quadrupole coupling constants of benzonitrile},
  author = {Kirstin Wohlfart and Melanie Schnell and Jens-Uwe Grabow and Jochen Küpper},
  journal= {arXiv preprint arXiv:0709.2984},
  year   = {2007}
}

Comments

6 pages, 2 tables (elsart)