The electronic band gap of a two-dimensional semiconductor within a device architecture is sensitive to variations in screening properties of adjacent materials in the device and to gate-controlled doping. Here, we employ micro-focused angle resolved photoemission spectroscopy to separate band gap renormalization effects stemming from environmental screening and electron-doping during \textit{in situ} gating of a single-layer WS2 device. The WS2 is supported on hBN and contains a section that is exposed to vacuum and another section that is encapsulated by a graphene contact. We directly observe the doping-induced semiconductor-metal transition and band gap renormalization in the two sections of WS2. Surprisingly, a larger band gap renormalization is observed in the vacuum-exposed section than in the graphene-encapsulated - and thus ostensibly better screened - section of the WS2. Using GW calculations, we determine that intrinsic screening due to stronger doping in vacuum exposed WS2 exceeds the external environmental screening in graphene-encapsulated WS2.
@article{arxiv.2503.16234,
title = {Quasiparticle gap renormalization driven by internal and external screening in a WS$_2$ device},
author = {Chakradhar Sahoo and Yann in 't Veld and Alfred J. H. Jones and Zhihao Jiang and Greta Lupi and Paulina E. Majchrzak and Kimberly Hsieh and Kenji Watanabe and Takashi Taniguchi and Philip Hofmann and Jill A. Miwa and Yong P. Chen and Malte Rösner and Søren Ulstrup},
journal= {arXiv preprint arXiv:2503.16234},
year = {2025}
}
Comments
31 pages, 12 figures (4 figures in main text and 8 figures in supporting information)