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Partial Equilibration Scenario in 3D athermal martensites quenched below first-order transition temperatures

Statistical Mechanics 2022-10-06 v1 Materials Science

Abstract

To test a Partial Equilibration Scenario (PES) of Ritort and colleagues, we do Monte Carlo simulations of discretized-strain spin models, for four 3D martensitic structural transitions under quenches to a bath temperature T<T0T <T_0 below a first-order transition. The ageing system faces entropy barriers, in {\it searches} for energy-lowering passages between quasi-microcanonical energy shells. We confirm the PES signature of an exponential-tail distribution of intermittent heat releases to the bath, scaled in an effective temperature, that in our case, depends on the quench. When its inverse βeff(T)1/Teff(T)\beta_{eff} (T) \equiv 1/T_{eff} (T) vanishes below a `martensite start' temperature T1T_1 of avalanche conversions, then entropy barriers vanish. When this search temperature Teff(T)T_{eff} (T) vanishes, PES cooling is arrested, as entropy barriers diverge. We find a {\it linear} vanishing of Teff(T)TdTT_{eff}(T)\sim T_d -T, below a delay-divergence temperature TdT_d in between, T1<Td<T0T_1 < T_d < T_0. Martensitic conversion delays e1/Teffe1/(TdT)e^{1/T_{eff}} \sim e^{1/(T_d -T)} thus have Vogel-Fulcher-Tammann like divergences. Post-quench delay data extracted from simulations and athermal martensitic alloys, are both consistent with predictions.

Keywords

Cite

@article{arxiv.2210.01997,
  title  = {Partial Equilibration Scenario in 3D athermal martensites quenched below first-order transition temperatures},
  author = {N. Shankaraiah and K. P. N. Murthy and S. R. Shenoy},
  journal= {arXiv preprint arXiv:2210.01997},
  year   = {2022}
}

Comments

18 pages, 24 figures, 4 videos