On 1/Z expansion for two-electron systems
Abstract
The -expansion for the Coulomb system of infinitely massive center of charge Z and two electrons is discussed. Numerical deficiency in Baker et al, {\em Phys. Rev. \bf A41}, 1247 (1990) is indicated which continue to raise doubts in correctness of their calculations of the higher order coefficients in -expansion expressed in Refs.[4-5]. It is shown that a minor modification of a few first coefficients found in Ref.[3] allows to calculate the ground state energies at (as well as at ) with a portion of 15th decimal digit in comparison with highly accurate calculations by C. Schwartz and by Nakashima-Nakatsuji. Ground state energies of two-electron ions and are found with 14 decimal digits.
Cite
@article{arxiv.1309.2707,
title = {On 1/Z expansion for two-electron systems},
author = {J. C. Lopez Vieyra and A. V. Turbiner},
journal= {arXiv preprint arXiv:1309.2707},
year = {2013}
}
Comments
7 pages, 2 Tables, two extra references added, Conclusions extended, two "Note added.I-II." added