English

Nuclear critical charge for two-electron ion in Lagrange mesh method

Quantum Physics 2017-01-05 v2 Atomic Physics

Abstract

The Schroedinger equation for two electrons in the field of a charged fixed center ZZ is solved with the Lagrange mesh method for charges close to the critical charge ZcrZ_{cr}. We confirm the value of the nuclear critical charge ZcrZ_{cr} recently calculated in Estienne et al. {\em Phys. Rev. Lett. \bf 112}, 173001 (2014) to 11 decimal digits using an inhomogeneous (non-uniform) three-dimensional lattice of size 70×70×2070 \times 70 \times 20. We show that the ground state energy for H^- is accurate to 14 decimals on the lattice 50×50×4050 \times 50 \times 40 in comparison with the highly accurate result by Nakashima-Nakatsuji, {\it J. Chem. Phys. \bf 127}, 224104 (2007).

Cite

@article{arxiv.1406.2136,
  title  = {Nuclear critical charge for two-electron ion in Lagrange mesh method},
  author = {H. Olivares Pilón and A. V. Turbiner},
  journal= {arXiv preprint arXiv:1406.2136},
  year   = {2017}
}

Comments

6 pages, no figures

R2 v1 2026-06-22T04:33:52.570Z