Peng (2008)(\cite{P08b}) proved the Central Limit Theorem under a sublinear expectation: \textit{Let (Xi)i≥1 be a sequence of i.i.d random variables under a sublinear expectation E^ with E^[X1]=E^[−X1]=0 and E^[∣X1∣3]<∞. Setting Wn:=nX1+⋯+Xn, we have, for each bounded and Lipschitz function φ, n→∞limE^[φ(Wn)]−NG(φ)=0, where NG is the G-normal distribution with G(a)=21E^[aX12], a∈R.} In this paper, we shall give an estimate of the rate of convergence of this CLT by Stein's method under sublinear expectations: \textit{Under the same conditions as above, there exists α∈(0,1) depending on σ and σ, and a positive constant Cα,G depending on α,σ and σ such that ∣φ∣Lip≤1supE^[φ(Wn)]−NG(φ)≤Cα,Gn2αE^[∣X1∣2+α], where σ2=E^[X12], σ2=−E^[−X12]>0 and NG is the G-normal distribution with G(a)=21E^[aX12]=21(σ2a+−σ2a−),a∈R.}