Nonlinear dynamics of dimers on periodic substrates
Abstract
We study the dynamics of a dimer moving on a periodic one-dimensional substrate as a function of the initial kinetic energy at zero temperature. The aim is to describe, in a simplified picture, the microscopic dynamics of diatomic molecules on periodic surfaces, which is of importance for thin film formation and crystal growth. We find a complex behaviour, characterized by a variety of dynamical regimes, namely oscillatory, ``quasi-diffusive'' (chaotic) and drift motion. Parametrically resonant excitations of internal vibrations can be induced both by oscillatory and drift motion of the centre of mass. For weakly bound dimers a chaotic regime is found for a whole range of velocities between two non-chaotic phases at low and high kinetic energy. The chaotic features have been monitored by studying the Lyapunov exponents and the power spectra. Moreover, for a short-range interaction, the dimer can dissociate due to the parametric excitation of the internal motion.
Cite
@article{arxiv.cond-mat/0301357,
title = {Nonlinear dynamics of dimers on periodic substrates},
author = {C. Fusco and A. Fasolino and T. Janssen},
journal= {arXiv preprint arXiv:cond-mat/0301357},
year = {2009}
}
Comments
9 pages, 13 figures, to be published in Eur. Phys. J. B