Nonequilibrium thermodynamics as a symplecto-contact reduction and relative information entropy
Abstract
Both statistical phase space (SPS), which is of -body particle system, and kinetic theory phase space (KTPS), which is the cotangent bundle of the probability space thereon, carry canonical symplectic structures. Starting from this first principle, we provide a canonical derivation of thermodynamic phase space (TPS) of nonequilibrium thermodynamics as a contact manifold in two steps. First, regarding the collective observation of observables in SPS as a moment map defined on KTPS, we apply the Marsden-Weinstein reduction and obtain a mesoscopic phase space in between KTPS and TPS as a (infinite dimensional) symplectic fibration. Then we show that the reduced relative information entropy defines a generating function that provides a covariant construction of a thermodynamic equilibrium as a Legendrian submanifold. This Legendrian submanifold is not necessarily graph-like. We interpret the Maxwell construction of \emph{equal-area law} as the procedure of finding a continuous, not necessarily differentiable, thermodynamic potential and explain the associated phase transition by identifying the procedure with that of finding a graph selector in symplecto-contact geometry and in the Aubry-Mather theory of dynamical system.
Keywords
Cite
@article{arxiv.2209.10660,
title = {Nonequilibrium thermodynamics as a symplecto-contact reduction and relative information entropy},
author = {Jin-wook Lim and Yong Geun Oh},
journal= {arXiv preprint arXiv:2209.10660},
year = {2023}
}
Comments
v4) 53 pages, presentation and English much improved, new references added, v5) 59 pages, the accepted version in Reports on Math. Physics