Non-equilibrium Roughness Evolution of Small Molecule Mixed Films Reflecting Equilibrium Phase Behavior
Applied Physics
2021-03-09 v1 Computational Physics
Abstract
Understanding non-equilibrium phenomena, such as growth, and connecting them to equilibrium phase behavior is a major challenge, in particular for complex multicomponent materials. We use X-ray reflectivity to determine the surface roughness of binary mixtures of several prototypical organic compounds. By analyzing the roughness as a function of composition, we find a systematic behavior depending on the bulk phase behavior in terms of intermixing, co-crystallization or phase separation. Supported by kinetic Monte Carlo simulations, we provide evidence that the growth behavior can be rationalized by a lowered step edge barrier in the mixed films which is induced by reduced in-plane crystallinity.
Cite
@article{arxiv.2103.04754,
title = {Non-equilibrium Roughness Evolution of Small Molecule Mixed Films Reflecting Equilibrium Phase Behavior},
author = {Alexander Hinderhofer and Jan Hagenlocher and Alexander Gerlach and Joachim Krug and Martin Oettel and Frank Schreiber},
journal= {arXiv preprint arXiv:2103.04754},
year = {2021}
}
Comments
10 pages, 9 figures