New approach for fabrication germanene with Dirac electrons preserved: A first principle study

How to obtain germanene with Dirac electrons preserved is still an open challenge. Here we report a sandwich-dehydrogenation approach, i.e., to fabricate germanene through dehydrogenating germanane in a sandwiched structure. The dehydrogenation can spontaneously occur for the sandwiched structure, which overcomes the problem of amorphization in the heating dehydrogenation approach. The obtained germanene preserve the Dirac electronic properties very well. Moreover, the Fermi velocity of germanene can be efficiently manipulated through controlling the interlayer spacing between germanane and the sandwiching surfaces. Our results indicate a guideline for fabrication of prefect two-dimensional materials.