Layered two-dimensional materials exhibit rich transport and optical phenomena in twisted or lattice-incommensurate heterostructures with spatial variations of interlayer hybridization arising from moir\'e interference effects. Here, we report experimental and theoretical studies of excitons in twisted heterobilayers and heterotrilayers of transition metal dichalcogenides. Using MoSe2-WSe2 stacks as representative realizations of twisted van der Waals bilayer and trilayer heterostructures, we observe contrasting optical signatures and interpret them in the theoretical framework of interlayer moir\'e excitons in different spin and valley configurations. We conclude that the photoluminescence of MoSe2-WSe2 heterobilayer is consistent with joint contributions from radiatively decaying valley-direct interlayer excitons and phonon-assisted emission from momentum-indirect reservoirs that reside in spatially distinct regions of moir\'e supercells, whereas the heterotrilayer emission is entirely due to momentum-dark interlayer excitons of hybrid-layer valleys. Our results highlight the profound role of interlayer hybridization for transition metal dichalcogenide heterostacks and other realizations of multi-layered semiconductor van der Waals heterostructures.
@article{arxiv.2006.09105,
title = {Moir\'e excitons in MoSe$_2$-WSe$_2$ heterobilayers and heterotrilayers},
author = {Michael Förg and Anvar S. Baimuratov and Stanislav Yu. Kruchinin and Ilia A. Vovk and Johannes Scherzer and Jonathan Förste and Victor Funk and Kenji Watanabe and Takashi Taniguchi and Alexander Högele},
journal= {arXiv preprint arXiv:2006.09105},
year = {2021}
}