English

Measurement of phosphorus segregation in silicon at the atomic-scale using STM

Condensed Matter 2009-11-10 v1

Abstract

In order to fabricate precise atomic-scale devices in silicon using a combination of scanning tunnelling microscopy (STM) and molecular beam epitaxy it is necessary to minimize the segregation/diffusion of dopant atoms during silicon encapsulation. We characterize the surface segregation/diffusion of phosphorus atoms from a δ\delta-doped layer in silicon after encapsulation at 250^{\circ}C and room temperature using secondary ion mass spectrometry (SIMS), Auger electron spectroscopy (AES), and STM. We show that the surface phosphorus density can be reduced to a few percent of the initial δ\delta-doped density if the phosphorus atoms are encapsulated with 5 or 10 monolayers of epitaxial silicon at room temperature. We highlight the limitations of SIMS and AES to determine phosphorus segregation at the atomic-scale and the advantage of using STM directly.

Keywords

Cite

@article{arxiv.cond-mat/0307495,
  title  = {Measurement of phosphorus segregation in silicon at the atomic-scale using STM},
  author = {Lars Oberbeck and Neil J. Curson and Toby Hallam and Michelle Y. Simmons and Robert G. Clark and Gerhard Bilger},
  journal= {arXiv preprint arXiv:cond-mat/0307495},
  year   = {2009}
}