English

Magnetoelastic dynamics of the "spin Jahn-Teller" transition in CoTi$_{2}$O$_{5}$

Strongly Correlated Electrons 2025-06-23 v1

Abstract

CoTi2_{2}O5_{5} has the paradox that low temperature static magnetic order is incompatible with the crystal structure owing to a mirror plane that exactly frustrates magnetic interactions. Despite no observable structural distortion with diffraction, CoTi2_{2}O5_{5} does magnetically order below TNT_{\rm N} \sim 25 K with the breaking of spin ground state degeneracy proposed to be a realization of the spin Jahn-Teller effect in analogy to the celebrated orbital Jahn-Teller transition. We apply neutron and Raman spectroscopy to study the dynamics of this transition in CoTi2_{2}O5_{5}. We find anomalous acoustics associated with a symmetry breaking strain that characterizes the spin Jahn-Teller transition. Crucially, the energy of this phonon coincides with the energy scale of the magnetic excitations, and has the same symmetry of an optic mode, observed with Raman spectroscopy, which atypically softens in energy with decreasing temperature. Taken together, we propose that the energetics of the spin Jahn-Teller effect in CoTi2_{2}O5_{5} are related to cooperative magnetoelastic fluctuations as opposed to conventional soft critical dynamics which typically drive large measurable static displacements.

Keywords

Cite

@article{arxiv.2506.16637,
  title  = {Magnetoelastic dynamics of the "spin Jahn-Teller" transition in CoTi$_{2}$O$_{5}$},
  author = {K. Guratinder and R. D. Johnson and D. Prabhakaran and R. A. Taylor and F. Lang and S. J. Blundell and L. S. Taran and S. V. Streltsov and T. J. Williams and S. R. Giblin and T. Fennell and K. Schmalzl and C. Stock},
  journal= {arXiv preprint arXiv:2506.16637},
  year   = {2025}
}

Comments

to be published in Physical Review Letters