English

Magnetic Behaviour of the $Bi_{2-y} Sr_y Ir_2 O_7$ Pyrochlore Solid Solution

Materials Science 2015-06-12 v1 Strongly Correlated Electrons

Abstract

The temperature dependence of magnetic susceptibility of the Bi2y_{2-y}Sry_{y}Ir2_{2}O7_{7} system was studied from 2 to 300 K. According to these measurements, the solid solution (0y0.9)(0\leq y\leq 0.9) does not show any magnetic transition; however, a noticeable deviation from the Curie-Weiss law occurs and the magnetic behavior of this system can be ascribed to short-range magnetic order that is also present in several geometrically frustrated systems. The Pauli magnetic susceptibility decreases as the Sr content increases, this can be associated with a shift towards Ir5+^{5+} in samples; also the Ir effective magnetic moment decreases. The estimated Wilson-ratio indicates the presence of strong electron-electron correlations.

Keywords

Cite

@article{arxiv.1301.2720,
  title  = {Magnetic Behaviour of the $Bi_{2-y} Sr_y Ir_2 O_7$ Pyrochlore Solid Solution},
  author = {C. Cosio-Castaneda and P. de la Mora and F. Morales and R. Escudero and G. Tavizon},
  journal= {arXiv preprint arXiv:1301.2720},
  year   = {2015}
}

Comments

Accepetd in: Journal of Solid State Chemistry