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Magnetic anisotropy in HoIr$_2$Si$_2$ ($I4/mmm$)

Strongly Correlated Electrons 2018-07-11 v1

Abstract

Single crystals of HoIr2_2Si2_2 with the body-centered ThCr2_2Si2_2-type structure (I4/mmmI4/mmm) were grown by Bridgman method from indium flux. Single crystal structure determination yielded a Si-z position of 0.378(1) in the structure. We excluded the presence of the high temperature phase with the primitive CaBe2_2Ge2_2-type structure (P4/nmmP 4/n m m) by powder X-ray diffraction. Magnetic measurements on the single crystals yield a Neel temperature of TN=22KT_{\rm N}=22\,\rm K. In the inverse magnetic susceptibility a strong anisotropy with Weiss temperatures ΘW001=26K\Theta_{W}^{001}=26\,\rm K and ΘW100=26K\Theta_{W}^{100}=-26\,\rm K occurs above TNT_{\rm N}. The effective magnetic moment μeff001=10.64μB\mu_{\rm eff}^{001}=10.64\mu_{B} and μeff100=10.53μB\mu_{\rm eff}^{100}=10.53\mu_{B} is close to the expected value for a free Ho3+^{3+} ion, μeffcalc=10.6μB\mu_{\rm eff}^{calc}=10.6\mu_{B}. The field dependent magnetization shows a step-like behaviour due to crystalline electric field effects.

Keywords

Cite

@article{arxiv.1807.03657,
  title  = {Magnetic anisotropy in HoIr$_2$Si$_2$ ($I4/mmm$)},
  author = {Kristin Kliemt and Michael Bolte and Cornelius Krellner},
  journal= {arXiv preprint arXiv:1807.03657},
  year   = {2018}
}