English

Length scale dependence of dynamical heterogeneity in a colloidal fractal gel

Soft Condensed Matter 2007-05-23 v2

Abstract

We use time-resolved dynamic light scattering to investigate the slow dynamics of a colloidal gel. The final decay of the average intensity autocorrelation function is well described by g_2(q,τ)1exp[(τ/τ_f)p]g\_2(q,\tau)-1 \sim \exp[-(\tau/\tau\_\mathrm{f})^p], with τ_fq1\tau\_\mathrm{f} \sim q^{-1} and pp decreasing from 1.5 to 1 with increasing qq. We show that the dynamics is not due to a continuous ballistic process, as proposed in previous works, but rather to rare, intermittent rearrangements. We quantify the dynamical fluctuations resulting from intermittency by means of the variance χ(τ,q)\chi(\tau,q) of the instantaneous autocorrelation function, the analogous of the dynamical susceptibility χ_4\chi\_4 studied in glass formers. The amplitude of χ\chi is found to grow linearly with qq. We propose a simple --yet general-- model of intermittent dynamics that accounts for the qq dependence of both the average correlation functions and χ\chi.

Keywords

Cite

@article{arxiv.cond-mat/0606051,
  title  = {Length scale dependence of dynamical heterogeneity in a colloidal fractal gel},
  author = {Agnes Duri and Luca Cipelletti},
  journal= {arXiv preprint arXiv:cond-mat/0606051},
  year   = {2007}
}

Comments

Revised and improved, to appear in Europhys. Lett