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We use time-resolved X-Photon Correlation Spectroscopy to investigate the slow dynamics of colloidal gels made of moderately attractive carbon black particles. We show that the slow dynamics is temporally heterogeneous and quantify its…

Soft Condensed Matter · Physics 2011-11-09 Veronique Trappe , Estelle Pitard , Laurence Ramos , Aymeric Robert , Hugo Bissig , Luca Cipelletti

Multispeckle x-ray photon correlation spectroscopy was employed to characterize the slow dynamics of a colloidal suspension formed by highly-charged, nanometer-sized disks. At scattering wave vectors $q$ corresponding to interparticle…

To gain insight into the kinetics of colloidal gel evolution at low particle volume fractions $\phi$, we utilize differential dynamic microscopy to investigate particle aggregation, geometric percolation, and the subsequent transition to…

Soft Condensed Matter · Physics 2020-03-02 Jae Hyung Cho , Roberto Cerbino , Irmgard Bischofberger

We present a systematic study of dynamical heterogeneity in a model for permanent gels, upon approaching the gelation threshold. We find that the fluctuations of the self intermediate scattering function are increasing functions of time,…

Soft Condensed Matter · Physics 2009-11-19 T. Abete , A. de Candia , E. Del Gado , A. Fierro , A. Coniglio

We here discuss the results of 3d MonteCarlo simulations of a minimal lattice model for gelling systems. We focus on the dynamics, investigated by means of the time autocorrelation function of the density fluctuations and the particle mean…

Soft Condensed Matter · Physics 2007-05-23 E. Del Gado , A. Fierro , L. de Arcangelis , A. Coniglio

Using molecular dynamics computer simulations we investigate the aging dynamics of a gel. We start from a fractal structure generated by the DLCA-DEF algorithm, onto which we then impose an interaction potential consisting of a short-range…

Soft Condensed Matter · Physics 2008-12-19 M-A. Suarez , N. Kern , E. Pitard , W. Kob

We numerically study dynamics and correlation length scales of a colloidal liquid in both quiescent and sheared conditions to further understand the origin of slow dynamics and dynamic heterogeneity in glass-forming systems. The simulation…

Soft Condensed Matter · Physics 2015-06-05 Wen-Sheng Xu , Zhao-Yan Sun , Li-Jia An

We study theoretically and numerically a family of multi-point dynamic susceptibilities that quantify the strength and characteristic lengthscales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments…

We compute the dynamical structure factor S(q,tau) of an elastic medium where force dipoles appear at random in space and in time, due to `micro-collapses' of the structure. Various regimes are found, depending on the wave vector q and the…

Condensed Matter · Physics 2009-11-07 J-P Bouchaud , E. Pitard

The normal modes and relaxation rates of weak colloidal gels are investigated in computations employing different models of the hydrodynamic interactions between colloids. The eigenspectrum is computed for freely draining,…

Fluid Dynamics · Physics 2018-01-17 Zsigmond Varga , James W. Swan

We report experimental measurements of particle dynamics in a colloidal glass in order to understand the dynamical heterogeneities associated with the cooperative motion of the particles in the glassy regime. We study the local and global…

Soft Condensed Matter · Physics 2007-05-23 P. Wang , C. Song , H. A. Makse

Rheological measurements of model colloidal gels reveal that large variations in the shear moduli as colloidal volume-fraction changes are not reflected by simple structural parameters such as the coordination number, which remains almost a…

Soft Condensed Matter · Physics 2018-08-07 D. Zeb Rocklin , Lilian C. Hsiao , Megan Szakasits , Michael J. Solomon , Xiaoming Mao

Transitions in structural heterogeneity of colloidal depletion gels formed through short-range attractive interactions are correlated with their dynamical arrest. The system is a density and refractive index matched suspension of 0.20…

Soft Condensed Matter · Physics 2009-11-11 C. J. Dibble , M. Kogan , M. J. Solomon

Investigating million-atom systems for very long simulation times, we demonstrate that the collective density-density correlation time ($\tau_{\alpha}$) in simulated supercooled water and silica becomes wavevector independent ($q^0$) when…

Statistical Mechanics · Physics 2019-05-20 Philip H. Handle , Lorenzo Rovigatti , Francesco Sciortino

We use molecular dynamics computer simulations to investigate the relaxation dynamics of a simple model for a colloidal gel at a low volume fraction. We find that due to the presence of the open spanning network this dynamics shows at low…

Soft Condensed Matter · Physics 2015-06-25 E. Del Gado , W. Kob

A multi-time probing of density fluctuations is introduced to investigate hidden time scales of heterogeneous dynamics in glass-forming liquids. Molecular dynamics simulations for simple glass-forming liquids are performed, and a three-time…

Soft Condensed Matter · Physics 2009-06-15 Kang Kim , Shinji Saito

We compare the slow dynamics of irreversible gels, colloidal gels, glasses and spin glasses by analyzing the behavior of the so called non-linear dynamical susceptibility, a quantity usually introduced to quantitatively characterize the…

Soft Condensed Matter · Physics 2015-06-25 A. Coniglio , T. Abete , A. de Candia , E. Del Gado , A. Fierro

In the present study, we performed molecular-dynamics simulations and investigated dynamical heterogeneity in a supercooled liquid under a steady shear flow. Dynamical heterogeneity can be characterized by three quantities: the correlation…

Soft Condensed Matter · Physics 2012-04-25 Hideyuki Mizuno Ryoichi Yamamoto

We examine a length scale that characterizes the spatial extent of heterogeneous dynamics in a glass-forming binary hard-sphere mixture up to the mode-coupling volume fraction phi_c. First, we characterize the system's dynamics. Then, we…

Soft Condensed Matter · Physics 2015-05-27 Elijah Flenner , Min Zhang , Grzegorz Szamel

We show by means of experiments, theory and simulations, that the slow dynamics of coarsening systems displays dynamic heterogeneity similar to that observed in glass-forming systems. We measure dynamic heterogeneity via novel multi-point…

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