Coherent manipulation of binary degrees of freedom is at the heart of modern quantum technologies. Graphene offers two binary degrees: the electron spin and the valley. Efficient spin control has been demonstrated in many solid state systems, while exploitation of the valley has only recently been started, yet without control on the single electron level. Here, we show that van-der Waals stacking of graphene onto hexagonal boron nitride offers a natural platform for valley control. We use a graphene quantum dot induced by the tip of a scanning tunneling microscope and demonstrate valley splitting that is tunable from -5 to +10 meV (including valley inversion) by sub-10-nm displacements of the quantum dot position. This boosts the range of controlled valley splitting by about one order of magnitude. The tunable inversion of spin and valley states should enable coherent superposition of these degrees of freedom as a first step towards graphene-based qubits.
@article{arxiv.1708.09170,
title = {Large tunable valley splitting in edge-free graphene quantum dots on boron nitride},
author = {Nils M. Freitag and Tobias Reisch and Larisa A. Chizhova and Peter Nemes-Incze and Christian Holl and Colin R. Woods and Roman V. Gorbachev and Yang Cao and Andre K. Geim and Kostya S. Novoselov and Joachim Burgdörfer and Florian Libisch and Markus Morgenstern},
journal= {arXiv preprint arXiv:1708.09170},
year = {2018}
}