Landscape equivalent of the shoving model
Soft Condensed Matter
2009-11-07 v4
Abstract
It is shown that the shoving model expression for the average relaxation time of viscous liquids follows largely from a classical "landscape" estimation of barrier heights from curvature at energy minima. The activation energy involves both instantaneous bulk and shear moduli, but the bulk modulus contributes less than 8% to the temperature dependence of the activation energy. This reflects the fact that the physics of the two models are closely related.
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Cite
@article{arxiv.cond-mat/0211042,
title = {Landscape equivalent of the shoving model},
author = {Jeppe C. Dyre and Niels Boye Olsen},
journal= {arXiv preprint arXiv:cond-mat/0211042},
year = {2009}
}
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4 pages