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Landscape equivalent of the shoving model

Soft Condensed Matter 2009-11-07 v4

Abstract

It is shown that the shoving model expression for the average relaxation time of viscous liquids follows largely from a classical "landscape" estimation of barrier heights from curvature at energy minima. The activation energy involves both instantaneous bulk and shear moduli, but the bulk modulus contributes less than 8% to the temperature dependence of the activation energy. This reflects the fact that the physics of the two models are closely related.

Keywords

Cite

@article{arxiv.cond-mat/0211042,
  title  = {Landscape equivalent of the shoving model},
  author = {Jeppe C. Dyre and Niels Boye Olsen},
  journal= {arXiv preprint arXiv:cond-mat/0211042},
  year   = {2009}
}

Comments

4 pages

R2 v1 2026-07-22T10:43:00.227Z