Jahn-Teller Anharmonic Coupling for an Octahedral System
Quantum Physics
2007-05-23 v1 Condensed Matter
Chemical Physics
Abstract
The coupling between doubly degenerate electronic states and doubly degenerate vibrations is analysed for an octahedral system on the basis of the introduction of an anharmonic Morse potential for the vibronic part. The vibrations are described by anharmonic coherent states and their linear coupling with the electronic states is considered. The matrix elements of the vibronic interaction are builded and the energy levels corresponding to the interaction Hamiltonian are derived.
Cite
@article{arxiv.quant-ph/0110153,
title = {Jahn-Teller Anharmonic Coupling for an Octahedral System},
author = {N. M. Avram and Gh. E. Draganescu and M. R. Kibler},
journal= {arXiv preprint arXiv:quant-ph/0110153},
year = {2007}
}
Comments
13 pages, LaTex file