English

Isotropic plasma-thermal atomic layer etching of aluminum nitride using SF$_6$ plasma and Al(CH$_3$)$_3$

Mesoscale and Nanoscale Physics 2022-11-09 v2

Abstract

We report the isotropic plasma atomic layer etching (ALE) of aluminum nitride using sequential exposures of SF6_6 plasma and trimethylaluminum (Al(CH3_3)3_3, TMA). ALE was observed at temperatures greater than 200 ^\circC, with a maximum etch rate of 1.9 \r{A}/cycle observed at 300 ^\circC as measured using ex-situ ellipsometry. After ALE, the etched surface was found to contain a lower concentration of oxygen compared to the original surface and exhibited a 35\sim 35% decrease in surface roughness. These findings have relevance for applications of AlN in nonlinear photonics and wide bandgap semiconductor devices.

Keywords

Cite

@article{arxiv.2209.00150,
  title  = {Isotropic plasma-thermal atomic layer etching of aluminum nitride using SF$_6$ plasma and Al(CH$_3$)$_3$},
  author = {Haozhe Wang and Azmain Hossain and David Catherall and Austin J. Minnich},
  journal= {arXiv preprint arXiv:2209.00150},
  year   = {2022}
}