Ionic Reactions in Two Dimensions with Disorder
Statistical Mechanics
2009-10-31 v1
Abstract
We analyze the dynamics of the ion-dipole pairing reaction in the two-dimensional Coulomb gas in the presence of disorder. Sufficiently singular disorder forces the critical temperature of the Kosterlitz-Thouless-Berezinskii fixed point to be non-universal. This disorder leads to anomalous ion pairing kinetics with a continuously variable decay exponent. Sufficiently strong disorder eliminates the transition altogether. For ions that are chemically reactive, anomalous kinetics with a continuously variable decay exponent also occurs in the high-temperature regime. The Coulomb interaction inhibits reactant segregation, and so the ionic reaction behaves like the nonionic reaction.
Keywords
Cite
@article{arxiv.cond-mat/9805076,
title = {Ionic Reactions in Two Dimensions with Disorder},
author = {Jeong-Man Park and Michael W. Deem},
journal= {arXiv preprint arXiv:cond-mat/9805076},
year = {2009}
}
Comments
To appear in Phys. Rev. E. 7 pages, 4 figures