English

Ionic Reactions in Two Dimensions with Disorder

Statistical Mechanics 2009-10-31 v1

Abstract

We analyze the dynamics of the ion-dipole pairing reaction in the two-dimensional Coulomb gas in the presence of disorder. Sufficiently singular disorder forces the critical temperature of the Kosterlitz-Thouless-Berezinskii fixed point to be non-universal. This disorder leads to anomalous ion pairing kinetics with a continuously variable decay exponent. Sufficiently strong disorder eliminates the transition altogether. For ions that are chemically reactive, anomalous kinetics with a continuously variable decay exponent also occurs in the high-temperature regime. The Coulomb interaction inhibits reactant segregation, and so the ionic A++BA^+ +B^- \to \emptyset reaction behaves like the nonionic A+AA + A \to \emptyset reaction.

Keywords

Cite

@article{arxiv.cond-mat/9805076,
  title  = {Ionic Reactions in Two Dimensions with Disorder},
  author = {Jeong-Man Park and Michael W. Deem},
  journal= {arXiv preprint arXiv:cond-mat/9805076},
  year   = {2009}
}

Comments

To appear in Phys. Rev. E. 7 pages, 4 figures